Usually means: Powerful demon, chief among evil.
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We found 14 dictionaries that define the word archfiend:

General (14 matching dictionaries)
  1. archfiend: Merriam-Webster
  2. archfiend: Oxford Learner's Dictionaries
  3. archfiend: American Heritage Dictionary of the English Language
  4. archfiend, the archfiend: Collins English Dictionary
  5. Archfiend, archfiend: Wordnik
  6. archfiend: Wiktionary
  7. archfiend: Webster's New World College Dictionary, 4th Ed.
  8. archfiend: The Wordsmyth English Dictionary-Thesaurus
  9. archfiend: Infoplease Dictionary
  10. Archfiend: Dictionary.com
  11. Archfiend: Wikipedia, the Free Encyclopedia
  12. archfiend: Webster's 1828 Dictionary
  13. archfiend: TheFreeDictionary.com
  14. archfiend: Merriam-Webster

Definitions from Wiktionary (archfiend)

noun:  A chief fiend (devil, demon or monster).
noun:  (preceded by “the”, often capitalized) Satan.
noun:  (transferred sense) A diabolically evil person.

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